The tables summarize the important elements for treating and understanding angular momentum.
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1, 2, 3
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7
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8
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4,5
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9
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6
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9c
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9a
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9 Angular solution: Spherical harmonics
l,m are integers |
9a General Legendre Equation
Solution: Associated Legendre Ploynomials |
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i. L
components do not commute with J2
ii. L2,S2,J2
commute
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10
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11
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12
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13
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14a,b
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15
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16
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16
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17a
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17b
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6 Are there restrictions on m values? YES
Therefore m has a maximum and a minimum value based on the total angular momentum. This is simply the generally accepted rule that a component can not be longer than the length of vector. A component is equal to the length when the vector and the component are aligned (parallel). This leads to the constraint
In order for the extreme values to be reached using the raising and lowering operators which increment m by ± 1. Either the state m=0 or m=± 1/2 must be included. |
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3-a Normalization
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Commutation relationships for L,S
components and J2
5a - Sum up both and get zero |
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Commutation relationships for L2,
S2 components and J2
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Commutation relationships for Li and
L2
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